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An outer join occurs when matching and nonmatching rows of either or both tables are contained in the join There are three kinds of outer joins: Left outer join Right outer join Full outer join All matched and unmatched rows of the first table and matched rows of the second table are included in the join Matched rows of the first table and matched and unmatched rows of the second table are included in the join Matched and unmatched rows of both tables are included in the join

Making the usual assumptions for low-pressure VLE, prepare a P-x-y diagram for this system at the given temperature

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Listing 11-64 shows how to create a left outer join This example creates a join between the Customers table and the Orders table using the customer number The *= operator is used in the WHERE clause to create a left outer join Think of the asterisk as a wildcard that tells the DBMS to use any row in the first table Before running Listing 11-64, insert the row shown in Table 11-10 into the Orders table; otherwise there will not be unmatched rows, because all the rows in both tables currently have matching values Listing 11-65 contains the DownRow() method used with Listing 11-64

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1427 The system water(1)ln-pentane(2)ln-heptane(3) exists as a vapor at 101325 Wa and 37315 K (100 C) with mole fractions zl = 045, z2 = 030, z3 = 025 The system is slowly cooled at constant pressure until it is completely condensed into a water phase and a hydrocarbon phase Assuming that the two liquid phases are immiscible, that the vapor phase is an ideal gas, and that the hydrocarbons obey Raoult's law, determine: (a) The dew-point temperature of the mixture and composition of the first condensate (b) The temperature at which the second liquid phase appears and its initial composition (c) The bubble-point temperature and the composition of the last bubble of vapor See Table 102, p 346, for vapor-pressure equations 1428 Work the preceding problem for mole fractions z l = 032, z2 = 045, z3 = 023 1429 The Case I behavior for SLE (Sec 146) has an analog for VLE Develop the analogy 1430 An assertion with respect to Case I1 behavior for SLE (Sec 146) was that the condition ily,S = 1 corresponds to complete immiscibility for all species in the solid state Prove this

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1431 Use results of Sec 146 to develop the following (approximate) rules of thumb: (a) The solubility of a solid in a liquid solvent increases with increasing T (b) The solubility of a solid in a liquid solvent is independent of the identity of the solvent species (c) Of two solids with roughly the same heat of fusion, that solid with the lower melting point is the more soluble in a given liquid solvent at a given T (d) Of two solids with similar melting points, that solid with the smaller heat of fusion is the more soluble in a given liquid solvent at a given T 1432 Estimate the solubility of naphthalene(1)in carbon dioxide(2)at a temperature of 35315 K (80 C) at pressures up to 300 bar Use the procedure described in Sec 147, with lI2= 0088 Compare the results with those shown by Fig 1422 Discuss any differences P,sat= 00102 bar at 35315 K (80 C) 1433 Estimate the solubility of naphthalene(1) in nitrogen(2) at a temperature of 30815 K (35 C) at pressures up to 300 bar Use the procedure described in Sec 147, with lI2= 0 Compare the results with those shown by Fig 1422 for the naphthalene/C02 system at 30815 K (35 C) with lI2= 0 Discuss any differences 1434 The qualitative features of SVE at high pressures shown by Fig 1422 are determined by the equation of state for the gas To what extent can these features be represented by the two-term virial equation in pressure, Eq (337) 1435 The UNILAN equation for pure-species adsorption is:

try { String query = new String ( " SELECT FirstName, LastName,OrderNumber " + " FROM Customers LEFT JOIN Orders " + " ON CustomersCustNumber = OrdersCustomerNumber"); DataRequest = DatabasecreateStatement(); Results = DataRequestexecuteQuery (query); DisplayResults (Results); DataRequestclose(); }

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