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most recently calculated values Once a value of V is established, values of xi are calculated by Eq (1416) and values of yi are given by yi = Kixi Multicomponent flash calculations based on the gammdphi formulation are readily carried out by computer as outlined in Fig 145 Table 142 shows the results of a P , T-flash calculation for the system n-hexane(l)/ethanol(2)/methylcyclopentane(3)/benzene(4) This is the same system for which results of a BUBL T calculation are presented in Table 141, and the same correlations and parameter values are used here The given P and T are here 1 atm and 33415 K (61 C) The given overall mole fractions for the system { z i ) are listed in Table 142 along with the calculated values of the liquid-phase and vapor-phase mole fractions and the K-values The molar fraction of the system that is vapor is found to be V = 08166

onclick, ondblclick, onkeydown, onkeypress, onkeyup, onmousedown, onmousemove, onmouseout, onmouseover, onmouseup

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Table 142 System: n-HexanelEthanoll Methylcyclopentane(MCP)/Benzene Calculation of P,T-flash at 1 atm and 33415 K (61 C)

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Object nextElement( ) String nextToken( ) String nextToken(String delimiters)

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The gammdphi approach to VLE calculations, based on Eq (14 l), presumes knowledge of the vapor pressure of each species at the temperature of interest Situations do arise however where a species is either unstable at the system temperature or is supercritical, ie, the system temperature exceeds its critical temperature Therefore its vapor pressure cannot be measured, and its fugacity f i as a pure liquid at the system temperature cannot be calculated by Eq (1141) Consider a binary system wherein species 1, designated the solute, cannot exist as a pure liquid at the system temperature Although Eqs (141) and (142) can be applied to species 2, designated the solvent, they are not applicable to the solute, and an alternative approach is required Figure 146 shows a typical plot of the liquid-phase fugacity of the solute f l vs its mole fraction xl at constant temperature This figure differs from Fig 123 in that the curve representing f l does not extend all the way to xl = 1 Thus the location of fi, the liquid-phase fugacity of pure species 1, is not established, and the line representing the LewisRandall rule cannot be drawn The tangent line at the origin, representing Henry's law (Sec 121), provides alternative information Recall that the slope of the tangent line is Henry's constant, defined by Eq (122) Thus,

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The output from this program is shown here: title Java: The Complete Reference author Naughton and Schildt publisher Osborne/McGraw-Hill copyright 1999

XI-0

values are center, justify, left, and right If a value is set to char, alignment is set to align off the character defined by the char attribute, with offset applied by charoffset

A BitSet class creates a special type of array that holds bit values This array can increase in size as needed This makes it similar to a vector of bits The BitSet constructors are shown here: BitSet( ) BitSet(int size) The first version creates a default object The second version allows you to specify its initial size (that is, the number of bits that it can hold) All bits are initialized to zero BitSet implements the Cloneable interface and defines the methods listed in Table 16-2 Table 16-2 The Methods Defined by BitSet

either a named color, such as red, or a color specified in the hexadecimal #RRGGBB format, such as #FF0000

Henry's constant is a strong function of temperature, but only weakly dependent on pressure Note, however, that the definition of X l at temperature T presumes the pressure is the equilibrium value at xl -+ 0, ie, the vapor pressure of the pure solvent Ppt

This attribute, supported by a number of browsers, including Internet Explorer, is used to set the border color for table cells in the row The attribute should be used only with a positive value for the border attribute The value of the attribute can be either a named color, such as green, or a color specified in the hexadecimal #RRGGBB format, such as #00FF00 CSS should be used instead

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