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(3) the presence of a foreign atom at one of the lattice sites, or (4) atoms that are displaced from their normal positions in the array Figure 3210 illustrates these defects The first type of point defect, the absence of an atom from a lattice point, is called a vacancy Figure 3210a shows a vacancy on the (100) planes of an FCC lattice The sketch was not made to be a true representation in order to make the defect more apparent In reality, the atoms that are near neighbors to the vacant site would be displaced from their normal positions in the array toward centers closer to the vacancy Thus the lattice lines joining the centers of the atoms are not straight in the vicinity of the vacancy In three dimensions this means that the crystallographic planes are warped inward near a vacancy.

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Individual vacancies can cluster together to form larger voids Vacancies have no effect on the metallurgical control of the mechanical properties discussed in later sections However, they do affect properties such as conductivity and diffusivity The second type of point defect, the presence of an extra atom at the interstices of the lattice, is known as an interstitial defect This type of defect in the lattice structure is the basis for the strengthening mechanism known as interstitial alloying, where the solute atom fits in the interstices of the solvent lattice, and it accounts for the high strength in fully hardened (heat-treated) steel Commercially pure iron (ferrite with a BCC structure) has a yield strength of 70 to 140 MPa However, with 08 percent carbon dissolved interstitially in the iron and stress relieved after heat treating, it has a yield strength of 2400 to 2800 MPa.

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No other metal has such high room-temperature strength, and no other strengthening mechanism has a greater effect than the interstitial alloying of carbon in iron The details of these strengthening mechanisms are discussed later..

FIGURE 32.10 Some common point defects. (a) Vacancy; (b) interstitial atom I; (c) substitution of a smaller atom S; (d) substitution of a larger atom S.

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Figure 3210b shows an interstitial atom I in the solvent matrix However, it does not lie in the plane of the solvent lattice but lies either above or below the sketched plane Also, the foreign atom is always larger than the void space it occupies, and so it necessarily forces the surrounding solvent atoms out of their normal array Therefore, the crystallographic planes are warped outward in the vicinity of an interstitial defect The third type of point defect, the presence of a foreign atom at one of the lattice points, is referred to as a substitutional defect When an alloy is made by adding solute atoms that replace (substitute for) solvent atoms in the lattice structure, it is called a substitutional alloy This type is the most common one in the metal system Figure 32.

10c and d shows the substitution of a smaller and a larger atom S at one of the lattice points Unlike the interstitial atom, the substitutional one is in the plane of the solvent matrix The crystallographic planes are also warped in the vicinity of the substitutional defect, inward for the smaller atom and outward for the larger atom The distortion of the crystallographic planes is very important to an understanding of control of the strength of materials, which is presented later The fourth type of point defect, atoms that are displaced from their normal position, occurs in several forms The atoms in the contacting planes of two adjoining crystals are not in their normal positions as a result of the crystals having solidified from the liquid without being in perfect registry with each other.

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