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The origins of intermolecular forces stem from the essential concept that a molecule is a distribution of charges: a collection of positively charged nuclei, surrounded by a cloud of negatively charged electrons Intermolecular repulsions at sufficiently small separations therefore result from the overlap of electron clouds of interacting molecules, giving rise to a Coulombic repulsion At still smaller separations the positively charged nuclei "see" each other, again promoting repulsion The origins of intermolecular attractions are less obvious, and several mechanisms can contribute First, consider the electrostatic interaction of two rigid charge distributions A and B By Coulomb's law, the electrostatic potential energy of interaction U(e1) is:

DisplayResults (Results); DataRequestclose(); }

<faces-config> <ordering> <after> <name>B</name> </after> <before> <others /> </before> </ordering> </faces-config>

a compilation of expressions for U see G C Maitland, M Rigby, E B Smith, and W A Wakeham, Intermolecular Forces: Their Origin and Determination, app 1, Clarendon Press, Oxford, 1981

The application element is used to encapsulate the set of elements that specify application singleton classes, such as overriding or decorating the default ViewHandler or ActionListener This element has no other use than to denote the beginning and end of the application configuration details

MAX()

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Rule JSF Versions Parent Elements Child Elements Value 10, 11, 12, 20 faces-config action-listener, application-extension, default-render-kit-id, defaultvalidators (20), el-resolver, locale-config, message-bundle, navigation-handler, property-resolver, resource-bundle, resourcehandler (20), state-manager, system-event-listener (20), variableresolver, view-handler Note: The parenthetical numbers represent the JSF versions that the corresponding child element applies to if the child element does not apply to all JSF versions Annotation(s) Uniqueness Constraints None None

'A comprehensive discussion of these contributions to U ( r ) is given by J 0 Hirschfelder, C F Curtiss, and R B Bird, Molecular Theory of Gases and Liquids, pp 25-30, 209, 983-1020, John Wiley and Sons, New York, 1954

The MAX() built-in function returns the highest value contained in the column passed to the built-in function Listing 11-72 shows how to use the MAX() built-in function to determine the maximum value in the Quantity column of the Orders table This code segment is used with the Model B program, and Listing 11-69 contains the DownRow() method to retrieve and display the value from the ResultSet

The following example illustrates the usage of the application element:

CHAPTER 16 Introduction to Molecular Thermodynamics Table 161 Bimolecular Potential Energy as a Function of Separation for the LennardJones 1216 Potential

Part III:

try { String query = new String ("SELECT MAX(Quantity) " + "FROM Orders "); DataRequest = DatabasecreateStatement(); Results = DataRequestexecuteQuery (query); DisplayResults (Results); DataRequestclose(); }

Here, qi is a charge in distribution A, qj is a charge in distribution B, and rij is the separation between charges qi and qj Quantity 0 is the electric permittivity of vacuum, a physical constant3 equal to 8854 19 x lo-'' C V-' m-' (The unit of electric charge is the coulomb C, and the unit of electric potential difference is the volt V) The sums are taken over all charges in the distributions Equation (162) is exact, but awkward to use as it stands Application is facilitated when the charge separation rij is replaced by the center-of-mass separation r of the two distributions Statistical averaging of contributions from all orientations of charge distribution yields the following approximate expression for U(e1) for two neutral rigid charge distribution^:^

The application-factory element is used to specify the fully qualified class name of a javax facesapplicationApplicationFactory implementation class that will replace or decorate the JSF implementation s default application factory implementation The application factory is used to retrieve and store a javaxfacesapplicationApplication instance for the current Web application See 11 for more details

COUNT()

Rule JSF Versions Parent Elements Child Elements Annotation(s) Uniqueness Constraints Value 10, 11, 12, 20 factory None None None

J K-l ; p~ and p~ are the permanent Quantity k is Boltzmann's constant, equal to 1381 x dipole moments for charge distributions A and B associated with the molecules This contribution to the pair-potential function vanishes only when one of the permanent dipole moments is zero The averaging procedure which leads to Eq (163) produces several remarkable results:

The following example illustrates the usage of the application-factory element:

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