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stants of H+ with some basic (donor) solvents [23]. Complexation of up to two solvent molecules occurs by the addition of small amounts of donor solvents. 11) If water is added as donor solvent to the H+ solution in AN, up to four water molecules are combined with H+. The formation constants for the reactions H+ + W 3 4w 3 H+ , H+ + 2W 3 H+ , H+ + 3W 3 H+ and H+ + 4W 2 H+ have been deter2 2W 2 3w 2 W mined spectrophotometrically using Hammett indicators [24]. They are log b(H+ ) = 2.2, log b(H+ ) = 3.9, log b(H+ ) = 4.8 and log b(H+ ) = 5.3, respectively. w 2w 3w 4w Figure 3.8 shows the distribution of each species as a function of free water concentration. It is apparent that, even when the concentration of free water is as low as 0.01 M, the fraction of free H+ is only about 30% and, if the concentration of free water is 1 M, more than half of the H+ exists as H+ . Moreover, H+ in AN 4w gradually reacts with the AN molecules and loses its reactivity. The H+ in other protophobic aprotic solvents also tends to react with water, other basic impurities, read pdf file in asp.net c# How to read pdf files using C# . NET - JADN
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