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Both reach the same p p state geometry, which deviates slightly from local D2d symmetry toward the trans-2butene structure because of the steric interaction between the methyl groups When it reverts to the ground state (both electrons go into the same orbital), more of it becomes trans than cis Actually, in pure alkene, isomerism takes second place to another much faster photoreaction, dimerization This reaction is also readily understood in orbital terms, but discussion of it is reserved until 14 4 1 This question deals with the description of a typical dative bond (a) Draw a two-orbital interaction diagram for the B N bond, as in H3 B N H3 Label the diagram clearly (b) Sketch all of the orbitals Identify the orbitals (eg, nY pY p Y sY s , etc, as appropriate) (c) Comment on the polarity of the B N bond.

Why is the boron atom shown with a formal charge of 1 2 Reaction of alkenes with BrCl proceeds via the intermediate [alkene-Br] rather than the intermediate [alkene-Cl] Explain using a two-orbital interaction diagram (The structure of the complex between ethylene and BrCl in the gas phase has been determined by microwave spectroscopy It is T-shaped, with the BrCl molecule lying perpendicular to the ethylene plane and pointing bromine-end rst toward the midpoint of the C C bond: Legon, A C; Bloemink, H I; Hinds, K; Thorn, J C, Chem Eng News, 1994 Nov 7, 26 29) 3 Suggest a reason for the rapid expulsion of atomic bromine upon one-electron reduc tion of N-bromosuccinimide (Lind, J; Shen, X; Eriksen, T E; Merenyi, G; Eberson, L, J Am Chem Soc, 1991, 113, 4629) 4.

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Predict the structures and bonding in donor acceptor complexes of ammonia with F2 , Cl2 , and ClF What are the expected relative bond strengths Are your predictions in accord with the results of high-level theoretical calculations of R ggen and Dahl (R ggen, I; Dahl, T, J Am Chem Soc, 1992, 114, 511).

Good news for users of Windows XP who install SP2: Not only does the new and improved version of IE 6 include a pop-up blocker that works pretty well (see my discussion of its test results in 6 for more details), but it s also turned on by default. Thus, once you upgrade (or after you ve upgraded) you won t have to put up with such distractions any more unless you actually want to see them.

Responding to Voicemail. Payroll managers rarely have secretaries or administrative assistants to eld phone calls. Voicemail is now every professional s assistant. However, it must be used wisely. This means updating the outgoing message frequently. Some suggestions from time-conscious payroll managers are: Change the outgoing message when lying low to work on year end. If the manager is running Forms W-2 or is otherwise tied up with processing, let the caller know that it will be awhile before the call will be returned. Change the outgoing message when out of the of ce. If out at year end meetings or working off site, tell the callers. For example, I will be out of the of ce between 10:00 and 12:00 noon. Request that callers indicate the best time to return their call. This minimizes the chances of playing phone tag during this hectic time. Also, set aside blocks of time to answer voicemail. Better yet, because payroll may be tied up during normal business hours, ask the caller to e-mail his or her request during this busy time. Reading E-Mails. Some payroll managers use e-mail to respond to voicemail and schedule time just to read messages. While it is preferable to answer each e-mail before reading the next, sometimes a read receipt and a promised date to respond will suf ce during year end. Otherwise, answer all e-mails immediately. The best advice regarding all mail, not just e-mail: open it, respond to it, le it, delete it, and close it. Do not handle it more than once. Other time saving tips for managing e-mail include: Use the subject line to get the reader s attention and to indicate that the mail is not spam.

Once all updates have been downloaded and configuration options set, you can move on to scan your computer for viruses. This process usually takes some time, so you may want to schedule scanning for times when you aren t actively using your computer, such as late-night hours. If infected files are found during a scan, you can run the Repair Wizard to fix, quarantine, delete, or exclude the files, or view summary information. After the system scan, you can view reports on quarantined items, visit the Online Virus Encyclopedia, and browse the Activity log (see Figure 8-6).

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Table 6.6 Function OnPaint() OnLButtonDown()

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