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149 For one of the substances listed below determine P Satha the RedlicldKwong from equation at two temperatures: T = T,, (the normal boiling point), and T = 085TC For the second temperature, compare your result with a value from the literature (eg, Perry's Chemical Engineers' Handbook) Discuss your results (a) Acetylene; (b) Argon; (c) Benzene; (d) n-Butane; (e) Carbon monoxide; ( f ) n-Decane; (g) Ethylene; ( h ) n-Heptane; (i) Methane; (j) Nitrogen 1410 Work Pb 149 for one of the following: (a) The Soave/Redlich/Kwongequation; (b) The PengRobinson equation 1411 Departures from Raoult's law are primarily from liquid-phase nonidealities (yi # 1) But vapor-phase nonidealities ($i 1) also contribute Consider the special case where # the liquid phase is an ideal solution, and the vapor phase a nonideal gas mixture described by Eq (337) Show that departures from Raoult's law at constant temperature are likely to be negative State clearly any assumptions and approximations 1412 Determine a numerical value for the acentric factor w implied by: (a) The van der Waals equation; (b) The RedlicWKwong equation 1413 Starting with Eq (1467), derive the stability criteria of Eqs (1468) and (1469) 1414 An absolute upper bound on G~ for stability of an equimolar binary mixture is G~ = R T In 2 Develop this result What is the corresponding bound for an equimolar mixture containing N species 1415 A binary liquid system exhibits LLE at 29815 K (25 C) Determine from each of the following sets of miscibility data estimates for parameters A12 and A21 in the Margules equation at 29815 K(25"C):

10, 11, 12, 20 10, 11, 12, 20 20

1416 Work Pb 1415 for the van Laar equation 1417 Consider a binary vapor-phase mixturedescribed by Eqs (337) and (1158) Under what (highly unlikely) conditions would one expect the mixture to split into two immiscible vapor phases 1418 Figures 1413, 1414, and 1415 are based on Eqs (A) and (F) of Ex 145 with C : assumedpositive and given by C;/R = 3 ~ 1 x 2 Graph the corresponding figures for the following cases, in which C is assumed negative: : 975 (a) A = -- - 184+ 31nT T

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The joins shown in previous sections of this chapter link rows that have matching values in the column specified in the join A row in a table that doesn t match is excluded from the join There are two kinds of joins, each of which either excludes or includes rows in both tables of the join that don t match These are An inner join excludes rows of either table that don t have a matching value An outer join includes rows of either table that don t have a matching value The following sections discuss each type of join in detail However, some DBMSs may use their own syntax rather than the SQL syntax for some or all joins Therefore, consult with your database administrator or DBMS manufacturer for the proper syntax for joins if examples in this book don t work with your DBMS Code segments used in these sections are executed using the executeQuery() method Therefore, you ll need to use the Model B program Remember that joins can also be used with the UPDATE and DELETE statements, in which case the Model A program is used

TABLE 15-1

1419 It has been suggested that a value for GE of at least 05 RT is required for liquidlliquid phase splitting in a binary system Offer some justification for this statement 1420 Pure liquid species 2 and 3 are for practical purposes immiscible in one another Liquid species 1 is soluble in both liquid 2 and liquid 3 One mole each of liquids 1, 2, and 3 are shaken together to form an equilibrium mixture of two liquid phases: an a-phase containing species 1 and 2, and a /3-phase containing species 1 and 3 What are the mole fractions of species 1 in the a and /3 phases, if at the temperature of the experiment, the excess Gibbs energies of the phases are given by:

10, 11, 12, 20

11:

The Complete List of Elements of the JSF Con guration File (continued)

1421 It is demonstrated in Ex 147 that the Wilson equation for GE is incapable of representing LLE Show that the simple modification of Wilson's equation given by:

Joins discussed previously in this chapter use an inner join to include only rows of both tables that have matching values Unmatched rows are excluded, and therefore those rows are not returned in the ResultSet Listing 11-62 demonstrates the use of an inner join by joining the Orders table and the Products table using product number and joining the Orders table and the Customers table using the customer number Listing 11-63 contains the DownRow() method used with Listing 11-62 to copy and display the contents of the ResultSet

15:

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